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DC Field | Value | Language |
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dc.contributor.author | Rufaro Kawondera | en_US |
dc.contributor.author | Marco Bonechi | en_US |
dc.contributor.author | Irene Maccioni | en_US |
dc.contributor.author | Walter Giurlani | en_US |
dc.contributor.author | Tommaso Salzillo | en_US |
dc.contributor.author | Elisabetta Venuti | en_US |
dc.contributor.author | Debabrata Mishra | en_US |
dc.contributor.author | Claudio Fontanesi | en_US |
dc.contributor.author | Massimo Innocenti | en_US |
dc.contributor.author | Gift Mehlana | en_US |
dc.contributor.author | Wilbert Mtangi | en_US |
dc.contributor.editor | Xiao Feng | en_US |
dc.date.accessioned | 2023-09-13T07:38:10Z | - |
dc.date.available | 2023-09-13T07:38:10Z | - |
dc.date.issued | 2023-08-08 | - |
dc.identifier.uri | https://cris.library.msu.ac.zw//handle/11408/5786 | - |
dc.description.abstract | This work reports on the electrochemical behaviour of Fe and Zn based metal- organic framework (MOF) compounds, which are “doped” with chiral molecules, namely: cysteine and camphor sulfonic acid. Their electrochemical behaviour was thoroughly investigated via “solid-state” electrochemical measurements, exploiting an “ad hoc” tailored experimental set-up: a paste obtained by carefully mixing the MOF with graphite powder is deposited on a glassy carbon (GC) surface. The latter serves as the working electrode (WE) in cyclic voltammetry (CV) measurements. Infrared (IR), X-ray diffraction (XRD) and absorbance (UV-Vis) techniques are exploited for a further characterization of the MOFs’ structural and electronic properties. The experimental results are then compared with DFT based quantum mechanical calculations. The electronic and structural properties of the MOFs synthesized in this study depend mainly on the type of metal center, and to a minor extent on the chemical nature of the dopant. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Frontiers Media | en_US |
dc.relation | Part of this work was carried with the aid of a grant from UNESCO- TWAS and Swedish International Development Cooperation Agency (Sida) for Individual Scientist | en_US |
dc.relation | WM acknowledges financial support from PhosAgro/UNESCO/IUPAC for Green Chemistry: “Hydrogen generation through photoelectrocatalytic water splitting” | en_US |
dc.relation | CF gratefully thanks financial support from Dipartimento di Ingegneria “Enzo Ferrari” (DIEF), UniMORE, FARD 2021—linea di azione di tipo 3: “Materiali chirali per batterie al litio e celle a combustibile” and from Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali (INSTM), fondi triennali: “INSTM21MOFONTANESI”,TWAS UNESCO Expert Visiting Program | en_US |
dc.relation.ispartof | Frontiers in Chemistry | en_US |
dc.subject | Metal-organic framework | en_US |
dc.subject | chiral doping | en_US |
dc.subject | cyclic voltammetry | en_US |
dc.subject | solid state electrochemistry | en_US |
dc.subject | SEM | en_US |
dc.subject | XRD | en_US |
dc.title | Chiral “doped” MOFs: an electrochemical and theoretical integrated study | en_US |
dc.type | research article | en_US |
dc.identifier.doi | 10.3389/fchem.2023.1215619 | - |
dc.contributor.affiliation | Institute of Materials Science, Processing and Engineering Technology, Chinhoyi University of Technology, Chinhoyi, Zimbabwe | en_US |
dc.contributor.affiliation | Department of Chemistry, University of Firenze, Firenze, Italy | en_US |
dc.contributor.affiliation | Department of Chemistry, University of Firenze, Firenze, Italy | en_US |
dc.contributor.affiliation | Department of Chemistry, University of Firenze, Firenze, Italy; National Interuniversity Consortium of Materials Science and Technology (INSTM), Firenze, Italy | en_US |
dc.contributor.affiliation | Department of Industrial Chemistry “Toso Montanari”, University of Bologna, Bologna, Italy | en_US |
dc.contributor.affiliation | Department of Industrial Chemistry “Toso Montanari”, University of Bologna, Bologna, Italy | en_US |
dc.contributor.affiliation | Department of Physics and Astrophysics, University of Delhi, New Delhi, India | en_US |
dc.contributor.affiliation | National Interuniversity Consortium of Materials Science and Technology (INSTM), Firenze, Italy; Department of Engineering “Enzo Ferrari” (DIEF), University of Modena, Modena, Italy | en_US |
dc.contributor.affiliation | Department of Chemistry, University of Firenze, Firenze, Italy; National Interuniversity Consortium of Materials Science and Technology (INSTM), Firenze, Italy; Center for Colloid and Surface Science (CSGI), Florence, Italy | en_US |
dc.contributor.affiliation | Department of Chemical Sciences, Midlands State University, Gweru, Zimbabwe | en_US |
dc.contributor.affiliation | Institute of Materials Science, Processing and Engineering Technology, Chinhoyi University of Technology, Chinhoyi, Zimbabwe | en_US |
dc.contributor.editoraffiliation | Beijing Institute of Technology, China | en_US |
dc.relation.issn | 2296-2646 | en_US |
dc.description.startpage | 1 | en_US |
dc.description.endpage | 11 | en_US |
dc.relation.grantno | 21-303 RG/PHYS/AF/AC_G- FR3240319510 | en_US |
dc.relation.grantno | 4500415755 | en_US |
dc.relation.grantno | 3240322698 | en_US |
item.fulltext | With Fulltext | - |
item.openairetype | research article | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.languageiso639-1 | en | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
Appears in Collections: | Research Papers |
Files in This Item:
File | Description | Size | Format | |
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Chiral doped MOFs.pdf | Abstract | 5.95 kB | Adobe PDF | View/Open |
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