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DC Field | Value | Language |
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dc.contributor.author | Nonkululeko Miya | en_US |
dc.contributor.author | Nyasha Makuve | en_US |
dc.contributor.author | Edward Ocansey | en_US |
dc.contributor.author | Gift Mehlana | en_US |
dc.contributor.author | James Darkwa | en_US |
dc.contributor.author | Banothile C.E. Makhubela | en_US |
dc.date.accessioned | 2022-12-16T09:41:33Z | - |
dc.date.available | 2022-12-16T09:41:33Z | - |
dc.date.issued | 2022-09-19 | - |
dc.identifier.uri | https://cris.library.msu.ac.zw//handle/11408/5289 | - |
dc.description.abstract | Widespread consumption of fossil resources yielding waste CO2 has reached an all-time high and this poses an environmental threat that is contributing to global warming and climate change. Using CO2 as a C1 source may serve as an avenue to convert waste to valuable platform chemicals such as formates. In this contribution, we report on the design and synthesis of new pincer Pd(II) N^C^N and N^N^N complexes. Herein, we investigate the role of an N^C^N or N^N^N ligand backbone in Pd(II) pre-catalysts and the corresponding catalytic activity in CO2 hydrogenation. Catalytic activity and selectivity with TON (turnover number) up to 537, in a THF/H2O biphasic (affording catalyst separation) system, was achieved. The CO2-to-CH3OH conversion sequence in the presence of an amine using these Pd pincer catalysts is also investigated. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Elsevier | en_US |
dc.relation.ispartof | Inorganica Chimica Acta | en_US |
dc.subject | Imine | en_US |
dc.subject | Pd pincer complexes | en_US |
dc.subject | CO2 hydrogenation | en_US |
dc.subject | Homogenous catalysis | en_US |
dc.title | Palladium complexes bearing bis-aldimine N^C^N and N^N^N pincer ligands; A study of homogeneous/heterogeneous catalyzed CO2 hydrogenation | en_US |
dc.type | research article | en_US |
dc.identifier.doi | https://doi.org/10.1016/j.ica.2022.121207 | - |
dc.contributor.affiliation | Research Centre for Synthesis and Catalysis, Department of Chemical Sciences, University of Johannesburg | en_US |
dc.contributor.affiliation | Synthesis and Catalysis, Department of Chemical Sciences, University of Johannesburg | en_US |
dc.contributor.affiliation | Synthesis and Catalysis, Department of Chemical Sciences, University of Johannesburg | en_US |
dc.contributor.affiliation | Department of Chemical Technology, Faculty of Science and Technology, Midlands State University, | en_US |
dc.contributor.affiliation | Research Centre for Synthesis and Catalysis, Department of Chemical Sciences, University of Johannesburg; Department of Natural Resources and Materials, Botswana Institute of Technology Research and Innovation, | en_US |
dc.contributor.affiliation | Research Centre for Synthesis and Catalysis, Department of Chemical Sciences, University of Johannesburg; Department of Natural Resources and Materials, Botswana Institute of Technology Research and Innovation, | en_US |
dc.relation.issn | 0020-1693 | en_US |
dc.description.volume | 545 (2023) | en_US |
dc.description.startpage | 1 | en_US |
dc.description.endpage | 11 | en_US |
item.fulltext | With Fulltext | - |
item.openairetype | research article | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.languageiso639-1 | en | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
Appears in Collections: | Research Papers |
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File | Description | Size | Format | |
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Palladium complexes bearing bis.pdf | Abstract | 64.92 kB | Adobe PDF | View/Open |
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